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A (13)C-labeled triarylmethyl radical as EPR spin probe highly sensitive to molecular tumbling

A stable triarylmethyl spin probe whose Electron Paramagnetic Resonance (EPR) spectrum is highly sensitive to molecular tumbling is reported. The strong anisotropy of the hyperfine coupling tensor with the central carbon of a (13)C(1)-labeled triarylmethyl radical enables the measurement of the prob...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Poncelet, Martin, Driesschaert, Benoit
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7901239/
https://ncbi.nlm.nih.gov/pubmed/32542924
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006591
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