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A (13)C-labeled triarylmethyl radical as EPR spin probe highly sensitive to molecular tumbling

A stable triarylmethyl spin probe whose Electron Paramagnetic Resonance (EPR) spectrum is highly sensitive to molecular tumbling is reported. The strong anisotropy of the hyperfine coupling tensor with the central carbon of a (13)C(1)-labeled triarylmethyl radical enables the measurement of the prob...

詳細記述

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書誌詳細
出版年:Angew Chem Int Ed Engl
主要な著者: Poncelet, Martin, Driesschaert, Benoit
フォーマット: Artigo
言語:Inglês
出版事項: 2020
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC7901239/
https://ncbi.nlm.nih.gov/pubmed/32542924
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006591
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