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A (13)C-labeled triarylmethyl radical as EPR spin probe highly sensitive to molecular tumbling

A stable triarylmethyl spin probe whose Electron Paramagnetic Resonance (EPR) spectrum is highly sensitive to molecular tumbling is reported. The strong anisotropy of the hyperfine coupling tensor with the central carbon of a (13)C(1)-labeled triarylmethyl radical enables the measurement of the prob...

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Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Poncelet, Martin, Driesschaert, Benoit
Format: Artigo
Langue:Inglês
Publié: 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7901239/
https://ncbi.nlm.nih.gov/pubmed/32542924
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006591
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