Allosteric Guest Binding in Chiral Zirconium(IV) Double Decker Porphyrin Cages

Chiral zirconium(IV) double cage sandwich complex Zr(1)(2) has been synthesized in one step from porphyrin cage H(2)1. Zr(1)(2) was obtained as a racemate, which was resolved by HPLC and the enantiomers were isolated in >99.5 % ee. Their absolute configurations were assigned on the basis of X‐ray...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:European J Org Chem
Prif Awduron: Bruekers, Jeroen P. J., Hellinghuizen, Matthijs A., Vanthuyne, Nicolas, Tinnemans, Paul, Gilissen, Pieter J., Buma, Wybren Jan, Naubron, Jean‐Valère, Crassous, Jeanne, Elemans, Johannes A. A. W., Nolte, Roeland J. M.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: John Wiley and Sons Inc. 2021
Pynciau:
Full Papers
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898692/
https://ncbi.nlm.nih.gov/pubmed/33679232
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.202001392
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