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Host–Guest Exchange of Viologen Guests in Porphyrin Cage Compounds as Studied by Selective Exchange Spectroscopy (1D EXSY) NMR

Dynamics in complexes of porphyrin cage compounds and viologen‐derived guest molecules are investigated by selective exchange NMR spectroscopy (1D EXSY). Exchange rates were found to be independent of excess guest concentration, revealing a dissociative exchange mechanism, which is accompanied by ne...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Swartjes, Anne, White, Paul B., Lammertink, Marijn, Elemans, Johannes A. A. W., Nolte, Roeland J. M.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2020
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839762/
https://ncbi.nlm.nih.gov/pubmed/33016567
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202010335
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