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Enantioselective synthesis of chiral porphyrin macrocyclic hosts and kinetic enantiorecognition of viologen guests

The construction of macromolecular hosts that are able to thread chiral guests in a stereoselective fashion is a big challenge. We herein describe the asymmetric synthesis of two enantiomeric C(2)-symmetric porphyrin macrocyclic hosts that thread and bind different viologen guests. Time-resolved flu...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Gilissen, Pieter J., Slootbeek, Annemiek D., Ouyang, Jiangkun, Vanthuyne, Nicolas, Bakker, Rob, Elemans, Johannes A. A. W., Nolte, Roeland J. M.
Format: Artigo
Langue:Inglês
Publié: The Royal Society of Chemistry 2021
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179042/
https://ncbi.nlm.nih.gov/pubmed/34163926
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05233g
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