Allosteric Guest Binding in Chiral Zirconium(IV) Double Decker Porphyrin Cages

Chiral zirconium(IV) double cage sandwich complex Zr(1)(2) has been synthesized in one step from porphyrin cage H(2)1. Zr(1)(2) was obtained as a racemate, which was resolved by HPLC and the enantiomers were isolated in >99.5 % ee. Their absolute configurations were assigned on the basis of X‐ray...

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Dades bibliogràfiques
Publicat a:European J Org Chem
Autors principals: Bruekers, Jeroen P. J., Hellinghuizen, Matthijs A., Vanthuyne, Nicolas, Tinnemans, Paul, Gilissen, Pieter J., Buma, Wybren Jan, Naubron, Jean‐Valère, Crassous, Jeanne, Elemans, Johannes A. A. W., Nolte, Roeland J. M.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2021
Matèries:
Full Papers
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898692/
https://ncbi.nlm.nih.gov/pubmed/33679232
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.202001392
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