Allosteric Guest Binding in Chiral Zirconium(IV) Double Decker Porphyrin Cages

Chiral zirconium(IV) double cage sandwich complex Zr(1)(2) has been synthesized in one step from porphyrin cage H(2)1. Zr(1)(2) was obtained as a racemate, which was resolved by HPLC and the enantiomers were isolated in >99.5 % ee. Their absolute configurations were assigned on the basis of X‐ray...

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Pubblicato in:European J Org Chem
Autori principali: Bruekers, Jeroen P. J., Hellinghuizen, Matthijs A., Vanthuyne, Nicolas, Tinnemans, Paul, Gilissen, Pieter J., Buma, Wybren Jan, Naubron, Jean‐Valère, Crassous, Jeanne, Elemans, Johannes A. A. W., Nolte, Roeland J. M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2021
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898692/
https://ncbi.nlm.nih.gov/pubmed/33679232
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.202001392
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