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Computational and Experimental Study of Turbo‐Organomagnesium Amide Reagents: Cubane Aggregates as Reactive Intermediates in Pummerer Coupling

The dynamic equilibria of organomagnesium reagents are known to be very complex, and the relative reactivity of their components is poorly understood. Herein, a combination of DFT calculations and kinetic experiments is employed to investigate the detailed reaction mechanism of the Pummerer coupling...

詳細記述

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書誌詳細
出版年:Chemistry
主要な著者: Planas, Ferran, Kohlhepp, Stefanie V., Huang, Genping, Mendoza, Abraham, Himo, Fahmi
フォーマット: Artigo
言語:Inglês
出版事項: John Wiley and Sons Inc. 2021
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898302/
https://ncbi.nlm.nih.gov/pubmed/33044772
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004164
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