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Nickel‐Catalyzed Intramolecular 1,2‐Aryl Migration of Mesoionic Carbenes (iMICs)
Intramolecular 1,2‐Dipp migration of seven mesoionic carbenes (iMIC(Ar)) 2 a–g (iMIC(Ar)=ArC{N(Dipp)}(2)CHC; Ar=aryl; Dipp=2,6‐iPr(2)C(6)H(3)) under nickel catalysis to give 1,3‐imidazoles (IMD(Ar)) 3 a–g (IMD(Ar)=ArC{N(Dipp)CHC(Dipp)N}) has been reported. The formation of 3 indicates the cleavage o...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Autores principales: | , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7898293/ https://ncbi.nlm.nih.gov/pubmed/33155756 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014328 |
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