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Nickel‐Catalyzed Inter‐ and Intramolecular Aryl Thioether Metathesis by Reversible Arylation

A nickel‐catalyzed aryl thioether metathesis has been developed to access high‐value thioethers. 1,2‐Bis(dicyclohexylphosphino)ethane (dcype) is essential to promote this highly functional‐group‐tolerant reaction. Furthermore, synthetically challenging macrocycles could be obtained in good yield in...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Delcaillau, Tristan, Bismuto, Alessandro, Lian, Zhong, Morandi, Bill
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7004142/
https://ncbi.nlm.nih.gov/pubmed/31829493
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201910436
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