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Enantioselective Nickel‐Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization

Enantioselective nickel‐catalyzed arylative cyclizations of substrates containing a Z‐allylic phosphate tethered to an alkyne are described. These reactions give multisubstituted chiral aza‐ and carbocycles, and are initiated by the addition of an arylboronic acid to the alkyne, followed by cyclizat...

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Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Yap, Connor, Lenagh‐Snow, Gabriel M. J., Karad, Somnath Narayan, Lewis, William, Diorazio, Louis J., Lam, Hon Wai
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2017
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5499723/
https://ncbi.nlm.nih.gov/pubmed/28544752
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201703380
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