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Enantioselective Nickel‐Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization

Enantioselective nickel‐catalyzed arylative cyclizations of substrates containing a Z‐allylic phosphate tethered to an alkyne are described. These reactions give multisubstituted chiral aza‐ and carbocycles, and are initiated by the addition of an arylboronic acid to the alkyne, followed by cyclizat...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Yap, Connor, Lenagh‐Snow, Gabriel M. J., Karad, Somnath Narayan, Lewis, William, Diorazio, Louis J., Lam, Hon Wai
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2017
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Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5499723/
https://ncbi.nlm.nih.gov/pubmed/28544752
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201703380
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