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Synthesis and Reactivity of Heteroleptic Ga‐P‐C Allyl Cation Analogues
Oxidative addition of cyclic alkyl(amino)carbene‐coordinated phosphinidenes ((Me)cAAC)PX to LGa affords gallium‐coordinated phosphinidenes LGa(X)‐P((Me)cAAC) (L=HC[C(Me)N(2,6‐i‐Pr(2)C(6)H(3))](2); X=Cl 1, Br 2), which react with NaBAr(F) (4) and LiAl(OR(F))(4) to [LGaP((Me)cAAC)][An] (An=B(C(6)H(3)(...
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| Publicado no: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7894565/ https://ncbi.nlm.nih.gov/pubmed/33034935 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202012595 |
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