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Synthesis of C-glycoside Analogues of α-GalactosylCeramide via Linear Allylic C-H Oxidation and Allyl Cyanate to Isocyanate Rearrangement

[Image: see text] C-Glycoside analogues of α-galactosylceramide were synthesized in which several significant modifications known to promote Th-1 cytokine production were included. The key transformations include C-H oxidation, Sharpless asymmetric epoxidation, olefin cross metathesis, and an allyl...

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Detalhes bibliográficos
Main Authors: Liu, Zheng, Bittman, Robert
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3263403/
https://ncbi.nlm.nih.gov/pubmed/22233351
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol2032448
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