A Mechanistic Study on Reactions of Group 13 Diyls LM with Cp*SbX(2): From Stibanyl Radicals to Antimony Hydrides

Oxidative addition of Cp*SbX(2) (X=Cl, Br, I; Cp*=C(5)Me(5)) to group 13 diyls LM (M=Al, Ga, In; L=HC[C(Me)N (Dip)](2), Dip=2,6‐iPr(2)C(6)H(3)) yields elemental antimony (M=Al) or the corresponding stibanylgallanes [L(X)Ga]Sb(X)Cp* (X=Br 1, I 2) and ‐indanes [L(X)In]Sb(X)Cp* (X=Cl 5, Br 6, I 7). 1 a...

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Bibliographic Details
Published in:Chemistry
Main Authors: Helling, Christoph, Wölper, Christoph, Cutsail, George E., Haberhauer, Gebhard, Schulz, Stephan
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2020
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7693246/
https://ncbi.nlm.nih.gov/pubmed/32428370
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001739
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