Synthesis and Reactivity of Heteroleptic Ga‐P‐C Allyl Cation Analogues

Oxidative addition of cyclic alkyl(amino)carbene‐coordinated phosphinidenes ((Me)cAAC)PX to LGa affords gallium‐coordinated phosphinidenes LGa(X)‐P((Me)cAAC) (L=HC[C(Me)N(2,6‐i‐Pr(2)C(6)H(3))](2); X=Cl 1, Br 2), which react with NaBAr(F) (4) and LiAl(OR(F))(4) to [LGaP((Me)cAAC)][An] (An=B(C(6)H(3)(...

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Foilsithe in:Angew Chem Int Ed Engl
Main Authors: Li, Bin, Wölper, Christoph, Haberhauer, Gebhard, Schulz, Stephan
Formáid: Artigo
Teanga:Inglês
Foilsithe: John Wiley and Sons Inc. 2020
Ábhair:
Research Articles
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7894565/
https://ncbi.nlm.nih.gov/pubmed/33034935
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202012595
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