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Identification of the Active Catalyst for Nickel-Catalyzed Stereospecific Kumada Coupling Reactions of Ethers

A series of nickel complexes in varying oxidation states were evaluated as precatalysts for stereospecific cross-coupling of benzylic ethers. These results demonstrate rapid redox reactions of precatalysts, such that the oxidative state of the precatalyst does not dictate the oxidation state of the...

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Publié dans:Chemistry
Auteurs principaux: Dawson, David D., Oswald, Victoria F., Borovik, A. S., Jarvo, Elizabeth R.
Format: Artigo
Langue:Inglês
Publié: 2020
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Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7872209/
https://ncbi.nlm.nih.gov/pubmed/31953874
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000215
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