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Coumarins by Direct Annulation: β‐Borylacrylates as Ambiphilic C(3)‐Synthons

Modular β‐borylacrylates have been validated as programmable, ambiphilic C(3)‐synthons in the cascade annulation of 2‐halo‐phenol derivatives to generate structurally and electronically diverse coumarins. Key to this [3+3] disconnection is the BPin unit which serves a dual purpose as both a traceles...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Wienhold, Max, Molloy, John J., Daniliuc, Constantin G., Gilmour, Ryan
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839779/
https://ncbi.nlm.nih.gov/pubmed/32975367
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202012099
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