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Trifluorinated Tetralins via I(I)/I(III)‐Catalysed Ring Expansion: Programming Conformation by [CH(2)CH(2)] → [CF(2)CHF] Isosterism
Saturated, fluorinated carbocycles are emerging as important modules for contemporary drug discovery. To expand the current portfolio, the synthesis of novel trifluorinated tetralins has been achieved. Fluorinated methyleneindanes serve as convenient precursors and undergo efficient difluorinative r...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2021
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8251640/ https://ncbi.nlm.nih.gov/pubmed/33721384 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202102222 |
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