Quaternary Charge-Transfer Complex Enables Photoenzymatic Intermolecular Hydroalkylation of Olefins

Intermolecular C–C bond-forming reactions are underdeveloped transformations in the field of biocatalysis. Here we report a photoenzymatic intermolecular hydroalkylation of olefins catalyzed by flavin-dependent ‘ene’reductases. Radical initiation occurs via photoexcitation of a rare high-order enzym...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Page, Claire G., Cooper, Simon J., DeHovitz, Jacob S., Oblinsky, Daniel G., Biegasiewicz, Kyle F., Antropow, Alyssa H., Armbrust, Kurt W., Ellis, J. Michael, Hamann, Lawrence G., Horn, Evan J., Oberg, Kevin M., Scholes, Gregory D., Hyster, Todd K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7832516/
https://ncbi.nlm.nih.gov/pubmed/33369395
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c11462
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