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Photoenzymatic Generation of Unstabilized Alkyl Radicals: An Asymmetric Reductive Cyclization
Flavin-dependent ‘ene’-reductases (ERED) can generate stabilized alkyl radicals when irradiated with visible light, however, they are not known to form unstabilized radicals. Here, we report an enantioselective radical cyclization using alkyl iodides as precursors to unstabilized nucleophilic radica...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7778473/ https://ncbi.nlm.nih.gov/pubmed/32857506 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c07918 |
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