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Photoexcitation of flavoenzymes enables a stereoselective radical cyclization
Photoexcitation is a common strategy for initiating radical reactions in chemical synthesis. We found that photoexcitation of flavin-dependent ‘ene’-reductases changes their catalytic function, enabling these enzymes to promote an asymmetric radical cyclization. This reactivity enables the construct...
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| Publié dans: | Science |
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| Auteurs principaux: | , , , , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7028431/ https://ncbi.nlm.nih.gov/pubmed/31221855 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaw1143 |
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