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Strong metal–metal Pauli repulsion leads to repulsive metallophilicity in closed-shell d(8) and d(10) organometallic complexes

Metallophilicity is defined as the interaction among closed-shell metal centers, the origin of which remains controversial, particularly for the roles of spd orbital hybridization (mixing of the spd atomic orbitals of the metal atom in the molecular orbitals of metal complex) and the relativistic ef...

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Dades bibliogràfiques
Publicat a:Proc Natl Acad Sci U S A
Autors principals: Wan, Qingyun, Yang, Jun, To, Wai-Pong, Che, Chi-Ming
Format: Artigo
Idioma:Inglês
Publicat: National Academy of Sciences 2021
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7817198/
https://ncbi.nlm.nih.gov/pubmed/33372160
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.2019265118
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