Tri‐ and Tetranuclear Metal‐String Complexes with Metallophilic d(10)–d(10) Interactions

The reaction of 2,6‐F(2)C(6)H(3)SiMe(3) with Ph(2)PLi provided 2,6‐(Ph(2)P)(2)C(6)H(3)SiMe(3) (1), which can be regarded as precursor for the novel anionic tridentate ligand [2,6‐(Ph(2)P)(2)C(6)H(3)](−) (PCP)(−). The reaction of 1 with [AuCl(tht)] (tht=tetrahydrothiophene) afforded 2,6‐(Ph(2)PAuCl)(...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Olaru, Marian, Kögel, Julius F., Aoki, Risa, Sakamoto, Ryota, Nishihara, Hiroshi, Lork, Enno, Mebs, Stefan, Vogt, Matthias, Beckmann, Jens
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
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Full Papers
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6972983/
https://ncbi.nlm.nih.gov/pubmed/31584732
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201904106
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