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Tri‐ and Tetranuclear Metal‐String Complexes with Metallophilic d(10)–d(10) Interactions
The reaction of 2,6‐F(2)C(6)H(3)SiMe(3) with Ph(2)PLi provided 2,6‐(Ph(2)P)(2)C(6)H(3)SiMe(3) (1), which can be regarded as precursor for the novel anionic tridentate ligand [2,6‐(Ph(2)P)(2)C(6)H(3)](−) (PCP)(−). The reaction of 1 with [AuCl(tht)] (tht=tetrahydrothiophene) afforded 2,6‐(Ph(2)PAuCl)(...
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| Udgivet i: | Chemistry |
|---|---|
| Main Authors: | , , , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6972983/ https://ncbi.nlm.nih.gov/pubmed/31584732 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201904106 |
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