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Strong metal–metal Pauli repulsion leads to repulsive metallophilicity in closed-shell d(8) and d(10) organometallic complexes
Metallophilicity is defined as the interaction among closed-shell metal centers, the origin of which remains controversial, particularly for the roles of spd orbital hybridization (mixing of the spd atomic orbitals of the metal atom in the molecular orbitals of metal complex) and the relativistic ef...
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| Veröffentlicht in: | Proc Natl Acad Sci U S A |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
National Academy of Sciences
2021
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7817198/ https://ncbi.nlm.nih.gov/pubmed/33372160 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.2019265118 |
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