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Relevance of Orbital Interactions and Pauli Repulsion in the Metal–Metal Bond of Coinage Metals

[Image: see text] The importance of relativity and dispersion in metallophilicity has been discussed in numerous studies. The existence of hybridization in the bonding between closed shell d(10)–d(10) metal atoms has also been speculated, but the presence of attractive MO interaction in the metal–me...

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Veröffentlicht in:Inorg Chem
Hauptverfasser: Brands, Maria B., Nitsch, Jörn, Guerra, Célia Fonseca
Format: Artigo
Sprache:Inglês
Veröffentlicht: American Chemical Society 2018
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5842375/
https://ncbi.nlm.nih.gov/pubmed/29431436
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.7b02994
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