Stabilization of Pentaphospholes as η(5)‐Coordinating Ligands

Electrophilic functionalisation of [Cp*Fe(η(5)‐P(5))] (1) yields the first transition‐metal complexes of pentaphospholes (cyclo‐P(5)R). Silylation of 1 with [(Et(3)Si)(2)(μ‐H)][B(C(6)F(5))(4)] leads to the ionic species [Cp*Fe(η(5)‐P(5)SiEt(3))][B(C(6)F(5))(4)] (2), whose subsequent reaction with H(...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Riesinger, Christoph, Balázs, Gábor, Bodensteiner, Michael, Scheer, Manfred
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7814675/
https://ncbi.nlm.nih.gov/pubmed/32956573
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011571
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