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The Parent Diarsene HAs=AsH as Side‐on Bound Ligand in an Iron Carbonyl Complex
The terminal diarsene HAs=AsH ligand attracts special interest concerning its bonding relation in comparison to its isolable relative, ethene. Herein, by the methanolysis of [{Fe(CO)(4)}As(SiMe(3))(3)] (1) the synthesis of [{Fe(CO)(4)}(η(2)‐As(2)H(2))] (2) is reported, containing a parent diarsene a...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6856853/ https://ncbi.nlm.nih.gov/pubmed/31424604 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909423 |
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