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The Butterfly Complex [{Cp*Cr(CO)(3)}(2)(μ,η(1:1)‐P(4))] as a Versatile Ligand and Its Unexpected P(1)/P(3) Fragmentation

The versatile coordination behavior of the P(4) butterfly complex [{Cp*Cr(CO)(3)}(2)(μ,η(1:1)‐P(4))] (1) towards Lewis acidic pentacarbonyl compounds of Cr, Mo and W is reported. The reaction of 1 with [W(CO)(4)(nbd)] (nbd=norbornadiene) yields the complex [{Cp*Cr(CO)(3)}(2)(μ(3),η(1:1:1:1)‐P(4)){W(...

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Dettagli Bibliografici
Pubblicato in:Chemistry
Autori principali: Grünbauer, Rebecca, Balázs, Gábor, Scheer, Manfred
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540658/
https://ncbi.nlm.nih.gov/pubmed/32657480
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002957
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