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Stabilization of Pentaphospholes as η(5)‐Coordinating Ligands
Electrophilic functionalisation of [Cp*Fe(η(5)‐P(5))] (1) yields the first transition‐metal complexes of pentaphospholes (cyclo‐P(5)R). Silylation of 1 with [(Et(3)Si)(2)(μ‐H)][B(C(6)F(5))(4)] leads to the ionic species [Cp*Fe(η(5)‐P(5)SiEt(3))][B(C(6)F(5))(4)] (2), whose subsequent reaction with H(...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7814675/ https://ncbi.nlm.nih.gov/pubmed/32956573 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011571 |
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