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Rhodium‐Catalyzed Cyclization of Terminal and Internal Allenols: An Atom Economic and Highly Stereoselective Access Towards Tetrahydropyrans

A comprehensive study of a diastereoselective Rh‐catalyzed cyclization of terminal and internal allenols is reported. The methodology allows the atom economic and highly syn‐selective access to synthetically important 2,4‐disubstituted and 2,4,6‐trisubstituted tetrahydropyrans (THP). Furthermore, it...

詳細記述

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書誌詳細
出版年:Angew Chem Int Ed Engl
主要な著者: Schmidt, Johannes P., Breit, Bernhard
フォーマット: Artigo
言語:Inglês
出版事項: John Wiley and Sons Inc. 2020
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756761/
https://ncbi.nlm.nih.gov/pubmed/32940396
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009166
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