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Rhodium-catalyzed asymmetric intramolecular hydroarylation of allenes: access to functionalized benzocycles
A rhodium-catalyzed regio- and enantioselective cyclization of tethered allenylbenzenes is reported. Employing a Rh(I)/Josiphos catalytic system a diverse set of 6-membered, α-chiral benzocycles were obtained, scaffolds found in many bioactive compounds. Moreover, a gram scale reaction as well as th...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Chem Sci |
|---|---|
| Prif Awduron: | , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
Royal Society of Chemistry
2019
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6977554/ https://ncbi.nlm.nih.gov/pubmed/32015818 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03894a |
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