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Gold(I)-Catalyzed Intramolecular Hydroarylation of Allenes

[Image: see text] Gold(I) complexes react with 4-allenyl arenes in an exo fashion to furnish vinyl-substituted benzocycles. Phosphite gold(I) monocations were found to be optimal, and the catalyst was tolerant of ethers, esters, and pyrroles. Reactions proceeded in unpurified solvent at room tempera...

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Hlavní autoři: Tarselli, Michael A., Gagné, Michel R.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2008
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2924810/
https://ncbi.nlm.nih.gov/pubmed/18278940
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo7024948
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