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Gold(I)-Catalyzed Intramolecular Hydroarylation of Allenes
[Image: see text] Gold(I) complexes react with 4-allenyl arenes in an exo fashion to furnish vinyl-substituted benzocycles. Phosphite gold(I) monocations were found to be optimal, and the catalyst was tolerant of ethers, esters, and pyrroles. Reactions proceeded in unpurified solvent at room tempera...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2008
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2924810/ https://ncbi.nlm.nih.gov/pubmed/18278940 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo7024948 |
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