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A Unified Framework for Understanding Nucleophilicity and Protophilicity in the S(N)2/E2 Competition
The concepts of nucleophilicity and protophilicity are fundamental and ubiquitous in chemistry. A case in point is bimolecular nucleophilic substitution (S(N)2) and base‐induced elimination (E2). A Lewis base acting as a strong nucleophile is needed for S(N)2 reactions, whereas a Lewis base acting a...
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| Publié dans: | Chemistry |
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| Auteurs principaux: | , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
John Wiley and Sons Inc.
2020
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7756690/ https://ncbi.nlm.nih.gov/pubmed/32866336 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003831 |
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