A Unified Framework for Understanding Nucleophilicity and Protophilicity in the S(N)2/E2 Competition

The concepts of nucleophilicity and protophilicity are fundamental and ubiquitous in chemistry. A case in point is bimolecular nucleophilic substitution (S(N)2) and base‐induced elimination (E2). A Lewis base acting as a strong nucleophile is needed for S(N)2 reactions, whereas a Lewis base acting a...

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Bibliografiska uppgifter
I publikationen:Chemistry
Huvudupphovsmän: Vermeeren, Pascal, Hansen, Thomas, Jansen, Paul, Swart, Marcel, Hamlin, Trevor A., Bickelhaupt, F. Matthias
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2020
Ämnen:
Full Papers
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756690/
https://ncbi.nlm.nih.gov/pubmed/32866336
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003831
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