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S(N)2 versus E2 Competition of F(–) and PH(2)(–) Revisited
[Image: see text] We have quantum chemically analyzed the competition between the bimolecular nucleophilic substitution (S(N)2) and base-induced elimination (E2) pathways for F(–) + CH(3)CH(2)Cl and PH(2)(–) + CH(3)CH(2)Cl using the activation strain model and Kohn–Sham molecular orbital theory at Z...
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| Udgivet i: | J Org Chem |
|---|---|
| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American Chemical
Society
2020
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| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7656514/ https://ncbi.nlm.nih.gov/pubmed/33079542 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c02112 |
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