Molecular Zinc Hydride Cations [ZnH](+): Synthesis, Structure, and CO(2) Hydrosilylation Catalysis

Protonolysis of [ZnH(2)](n) with the conjugated Brønsted acid of the bidentate diamine TMEDA (N,N,N′,N′‐tetramethylethane‐1,2‐diamine) and TEEDA (N,N,N′,N′‐tetraethylethane‐1,2‐diamine) gave the zinc hydride cation [(L(2))ZnH](+), isolable either as the mononuclear THF adduct [(L(2))ZnH(thf)](+)[BAr...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Ritter, Florian, Spaniol, Thomas P., Douair, Iskander, Maron, Laurent, Okuda, Jun
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2020
Subjects:
Research Articles
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756573/
https://ncbi.nlm.nih.gov/pubmed/32931656
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011480
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