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Alkali Metal Triphenyl‐ and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand
Potassium silanide [KSiH(3)](∞) contains 4.2 wt % of hydrogen and has been intensely studied as hydrogen storage material. The macrocyclic ligand Me(4)TACD (1,4,7,10‐tetramethyl‐1,4,7,10‐tetraaminocyclododecane, L) stabilizes the full range of triphenylsilyl complexes [(L)MSiPh(3)](n) (M=Li–Cs), whi...
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| Gepubliceerd in: | Chemistry |
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| Hoofdauteurs: | , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
John Wiley and Sons Inc.
2020
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7079104/ https://ncbi.nlm.nih.gov/pubmed/31943432 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000187 |
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