Alkali Metal Triphenyl‐ and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand

Potassium silanide [KSiH(3)](∞) contains 4.2 wt % of hydrogen and has been intensely studied as hydrogen storage material. The macrocyclic ligand Me(4)TACD (1,4,7,10‐tetramethyl‐1,4,7,10‐tetraaminocyclododecane, L) stabilizes the full range of triphenylsilyl complexes [(L)MSiPh(3)](n) (M=Li–Cs), whi...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chemistry
Egile Nagusiak: Schuhknecht, Danny, Leich, Valeri, Spaniol, Thomas P., Douair, Iskander, Maron, Laurent, Okuda, Jun
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: John Wiley and Sons Inc. 2020
Gaiak:
Communications
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7079104/
https://ncbi.nlm.nih.gov/pubmed/31943432
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000187
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