Terminal Alkyne Coupling Reactions Through a Ring: Effect of Ring Size on Rate and Regioselectivity

Terminal alkyne coupling reactions promoted by rhodium(I) complexes of macrocyclic NHC‐based pincer ligands—which feature dodecamethylene, tetradecamethylene or hexadecamethylene wingtip linkers viz. [Rh(CNC‐n)(C(2)H(4))][BAr(F) (4)] (n=12, 14, 16; Ar(F)=3,5‐(CF(3))(2)C(6)H(3))—have been investigate...

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Publicado no:Chemistry
Main Authors: Storey, Caroline M., Gyton, Matthew R., Andrew, Rhiann E., Chaplin, Adrian B.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756505/
https://ncbi.nlm.nih.gov/pubmed/32677713
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002962
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