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Regioselective Formation of α-Vinylpyrroles from the Ruthenium-Catalyzed Coupling Reaction of Pyrroles and Terminal Alkynes Involving C–H Bond Activation
[Image: see text] The cationic ruthenium catalyst, Ru(3)(CO)(12)/NH(4)PF(6), was found to be highly effective for the intermolecular coupling reaction of pyrroles and terminal alkynes to give gem-selective α-vinylpyrroles. The carbon isotope effect on the α-pyrrole carbon and the Hammett correlation...
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| Asıl Yazarlar: | , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2010
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2865850/ https://ncbi.nlm.nih.gov/pubmed/20384382 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo100269y |
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