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Regioselective Formation of α-Vinylpyrroles from the Ruthenium-Catalyzed Coupling Reaction of Pyrroles and Terminal Alkynes Involving C–H Bond Activation

[Image: see text] The cationic ruthenium catalyst, Ru(3)(CO)(12)/NH(4)PF(6), was found to be highly effective for the intermolecular coupling reaction of pyrroles and terminal alkynes to give gem-selective α-vinylpyrroles. The carbon isotope effect on the α-pyrrole carbon and the Hammett correlation...

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Detaylı Bibliyografya
Asıl Yazarlar: Gao, Ruili, Yi, Chae S.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2010
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC2865850/
https://ncbi.nlm.nih.gov/pubmed/20384382
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo100269y
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