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Regioselective Intermolecular Coupling Reaction of Arylketones and Alkenes Involving C-H Bond Activation Catalyzed by an In-Situ Formed Cationic Ruthenium-Hydride Complex

The cationic ruthenium-hydride complex, formed in-situ from the treatment of the tetranuclear ruthenium-hydride complex {[(PCy(3))(CO)RuH](4)(μ(4)-O)(μ(3)-OH)(μ(2)-OH)} with HBF(4)·OEt(2), was found to be a highly effective catalyst for the intermolecular coupling reaction of arylketones and 1-alken...

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Hlavní autoři: Yi, Chae S., Lee, Do W.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2805103/
https://ncbi.nlm.nih.gov/pubmed/20161548
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om900416k
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