ロード中...

Intermolecular Dehydrative Coupling Reaction of Arylketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: A Novel Ketone Olefination Method via Vinyl C–H Bond Activation

The cationic ruthenium-hydride complex [(η(6)-C(6)H(6))(PCy(3))(CO)RuH](+)BF(4)(−) was found to be a highly effective catalyst for the intermolecular olefination reaction of arylketones with cycloalkenes. The preliminary mechanistic analysis revealed that electrophilic ruthenium-vinyl complex is the...

詳細記述

保存先:
書誌詳細
主要な著者: Yi, Chae S., Lee, Do W.
フォーマット: Artigo
言語:Inglês
出版事項: 2010
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2887707/
https://ncbi.nlm.nih.gov/pubmed/20567607
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om100051h
タグ: タグ追加
タグなし, このレコードへの初めてのタグを付けませんか!