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Scope and Mechanistic Study of the Ruthenium-Catalyzed Ortho-C-H Bond Activation and Cyclization Reactions of Arylamines with Terminal Alkynes
The cationic ruthenium-hydride complexes, [(PCy(3))(2)(CO)(CH(3)CN)(2)RuH](+)BF(4)(−) and formed in situ from Ru(3)(CO)(12)/HBF(4)·OEt(2), were found to be highly effective catalysts for the C-H bond activation reaction of arylamines and terminal alkynes. The regioselective catalytic synthesis of su...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2585980/ https://ncbi.nlm.nih.gov/pubmed/16316246 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja055608s |
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