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Scope and Mechanistic Investigations on the Solvent-Controlled Regio- and Stereoselective Formation of Enol Esters from the Ruthenium-Catalyzed Coupling Reaction of Terminal Alkynes and Carboxylic Acids

The ruthenium-hydride complex (PCy(3))(2)(CO)RuHCl was found to be a highly effective catalyst for the alkyne-to-carboxylic acid coupling reaction to give synthetically useful enol ester products. Strong solvent effect was observed for the ruthenium catalyst in modulating the activity and selectivit...

תיאור מלא

שמור ב:
מידע ביבליוגרפי
Main Authors: Yi, Chae S., Gao, Ruili
פורמט: Artigo
שפה:Inglês
יצא לאור: 2009
נושאים:
גישה מקוונת:https://ncbi.nlm.nih.gov/pmc/articles/PMC2782529/
https://ncbi.nlm.nih.gov/pubmed/20161379
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om9007357
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