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A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes

The preparation of a range of tetraaryl-substituted bicyclo[4.2.0]octa-1,5,7-trienes using a one-pot procedure starting from terminal aryl alkynes and catalysed by a rhodium(i) complex is reported. This synthesis proceeds by a reaction sequence involving head-to-tail homocoupling of the terminal alk...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Storey, Caroline M., Kalpokas, Audrius, Gyton, Matthew R., Krämer, Tobias, Chaplin, Adrian B.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7053420/
https://ncbi.nlm.nih.gov/pubmed/32180927
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc06153c
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