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Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex

The synthesis and organometallic chemistry of rhodium(I) complex [Rh(CNC–Me)(SOMe(2))][BAr(F) (4)], featuring NHC‐based pincer and labile dimethyl sulfoxide ligands, is reported. This complex reacts with biphenylene and chlorobenzene to afford products resulting from selective C–C and C–Cl bond acti...

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Bibliographic Details
Published in:Eur J Inorg Chem
Main Authors: Kynman, Amy E., Lau, Samantha, Dowd, Sean O., Krämer, Tobias, Chaplin, Adrian B.
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2020
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7702176/
https://ncbi.nlm.nih.gov/pubmed/33328794
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.202000780
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