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Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching
The mechanism and selectivity of terminal alkyne coupling reactions promoted by rhodium(I) complexes of NHC‐based CNC pincer ligands have been investigated. Synthetic and kinetic experiments support E‐ and gem‐enyne formation through a common reaction sequence involving hydrometallation and rate‐det...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6175324/ https://ncbi.nlm.nih.gov/pubmed/30004163 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201807028 |
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