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Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching

The mechanism and selectivity of terminal alkyne coupling reactions promoted by rhodium(I) complexes of NHC‐based CNC pincer ligands have been investigated. Synthetic and kinetic experiments support E‐ and gem‐enyne formation through a common reaction sequence involving hydrometallation and rate‐det...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: Storey, Caroline M., Gyton, Matthew R., Andrew, Rhiann E., Chaplin, Adrian B.
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2018
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6175324/
https://ncbi.nlm.nih.gov/pubmed/30004163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201807028
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