A Computational and Experimental Investigation of the Origin of Selectivity in the Chiral Phosphoric Acid Catalyzed Enantioselective Minisci Reaction

[Image: see text] The Minisci reaction is one of the most valuable methods for directly functionalizing basic heteroarenes to form carbon–carbon bonds. Use of prochiral, heteroatom-substituted radicals results in stereocenters being formed adjacent to the heteroaromatic system, generating motifs whi...

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Argitaratua izan da:J Am Chem Soc
Egile Nagusiak: Ermanis, Kristaps, Colgan, Avene C., Proctor, Rupert S. J., Hadrys, Barbara W., Phipps, Robert J., Goodman, Jonathan M.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: American Chemical Society 2020
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7747223/
https://ncbi.nlm.nih.gov/pubmed/33252228
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c09668
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