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A Computational and Experimental Investigation of the Origin of Selectivity in the Chiral Phosphoric Acid Catalyzed Enantioselective Minisci Reaction
[Image: see text] The Minisci reaction is one of the most valuable methods for directly functionalizing basic heteroarenes to form carbon–carbon bonds. Use of prochiral, heteroatom-substituted radicals results in stereocenters being formed adjacent to the heteroaromatic system, generating motifs whi...
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| Veröffentlicht in: | J Am Chem Soc |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American Chemical
Society
2020
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| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7747223/ https://ncbi.nlm.nih.gov/pubmed/33252228 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c09668 |
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