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Mechanisms of Formation and Rearrangement of Benziodoxole-Based CF(3) and SCF(3) Transfer Reagents
[Image: see text] Togni’s benziodoxole-based reagents are widely used in trifluoromethylation reactions. It has been established that the kinetically stable hypervalent iodine form (I–CF(3)) of the reagents is thermodynamically less stable than its acyclic ether isomer (O–CF(3)). On the other hand,...
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| Vydáno v: | J Org Chem |
|---|---|
| Hlavní autoři: | , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
American Chemical
Society
2020
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| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7735722/ https://ncbi.nlm.nih.gov/pubmed/33201704 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c02306 |
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