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Copper-Catalyzed, N-Directed Csp(3)–H Trifluoromethylthiolation (−SCF(3)) and Trifluoromethylselenation (−SeCF(3))

A direct and versatile copper-catalyzed trifluoromethylthiolation and trifluoromethylselenation of primary, secondary, and tertiary aliphatic C–H bonds was developed. The reaction provides direct access to molecules containing these emerging moieties in the presence of a wide range of common functio...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Modak, Atanu, Pinter, Emily N., Cook, Silas P.
Format: Artigo
Sprog:Inglês
Udgivet: 2019
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7193900/
https://ncbi.nlm.nih.gov/pubmed/31697070
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b10316
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